Synthesis, Crystal Structure and Catalytic Property of a Cobalt(III) Compound Derived From 2-Bromo-N’-(2-Hydroxy-5-Methylbenzylidene)Benzohydrazide

Jamileh Etemad Gholtash, Mahnaz Farahi,* Bahador Karami and Mahsa Abdollahi Department of Chemistry, Yasouj

Structures of the free hydrazone and the complex were further characterized by single crystal X-ray diffraction, which indicates that the V atom in the complex adopts

The coordination geometry around the cobalt atom in complex 1 and the manganese atom in complex 2 are octahedral, with two pyridine N atoms, two imino N atoms, and two enolate O

9 The hydrazone coordinates to the Co atom with the pyridine nitrogen, enolate oxygen and imino nitrogen atoms.. Ligand L is nearly coplanar, with the dihedral an- gles between

The Schiff base HL and the complex were screened in vitro for antibacterial activities against Bacillus subtilis, Staphylococcus aureus, Escherichia coli, and Pseudomonas

1 Department of Organic Chemistry, Faculty of Chemistry and Chemical Technology, Večna pot 113, 1000 Ljubljana, Slovenia.. 2 Present address:

1 Department of Organic Chemistry, Faculty of Chemistry and Chemical Technology, Večna pot 113, 1000 Ljubljana, Slovenia. 2 Present address:

In the complex the Mo atom is coordinated by the phenolic oxygen, imino nitro- gen, enolic oxygen of the hydrazone ligand, two oxo oxy- gen and one methanol oxygen, forming